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Regulation of Pore Structure and High-temperature Fracture Behavior of CAC-bonded Alumina-Spinel Castables Based on Hydration Design

作者:Wenjing LIU1Ning LIAO1,2,3Yawei LI1,2,3

作者單位:1.The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology2.National-provincial Joint Engineering Research Center of High Temperature Materials and Lining Technology3.Joint International Research Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology

刊名:China's Refractories

ISSN:1004-4493

出版年:2024-09-15

卷:33

期:3

起頁:22-29

止頁:

分類號(hào):TQ175.732

語種:英文

關(guān)鍵詞:

內(nèi)容簡(jiǎn)介

The lamellar hydrates of CAC were designed with the introduction of nano CaCO3 or Mg-Al hydrotalcite (M-A-H),and the effects on the green strength,pore structures,and high-temperature fracture behavior of alumina-spinel castables were investigated.The results show that nano CaCO3 or M-A-H stimulates rapidly the hydration of CAC and the formation of lamellar C4AcH11 or coexistence of C2AH8 and C4AcH11 at 25°C.The formation of lamellar hydrates can contribute to a more complicated pore structure,especially in the range of 400-2 000 nm.Meanwhile,the incorporation of well-distributed CaO or MgO sources from nano CaCO3 or M-A-H also regulates the distribution of CA6 and spinel (pre-formed and in-situ).Consequently,the optimized microstructure and complicated pore structure can induce the deflection and bridging of cracks,thus facilitating the consumption of fracture energy and enhancing the resistance to thermal stress damage.

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